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Marialite
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Discovered in 1866; IMA status: Valid (pre-IMA; Grandfathered)
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Chemistry
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Chemical
Formula: |
Na4Al3Si9O24Cl
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Sodium
Aluminum Silicate Cloride |
Molecular
Weight: |
845.11 gm
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Composition: |
Sodium |
10.88 % |
Na |
14.67 % |
Na2O |
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Aluminum |
9.58 % |
Al |
18.10 % |
Al2O3 |
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Silicon |
29.91 % |
Si |
63.99 % |
SiO2 |
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Chlorine |
4.20 % |
Cl |
4.20 % |
Cl |
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- |
Cl |
-0.95 % |
-O=Cl2 |
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Oxygen |
45.44 % |
O |
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100.00 % |
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100.00 % |
= TOTAL OXIDE |
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Classification
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Mineral
Classification: |
Silicates
(Germanates)
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Strunz 8th
Ed. ID:
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8/J.13-10
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Nickel-Strunz 10th
Ed. ID:
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9.FB.15
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9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
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Related
to: |
Scapolite
Gourp.
Marialite-Meionite Sseries.
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Members
of Group: |
Scapolite
Gourp:
Kembleite, Marialite, Meionite, Scapolite, Silvialie
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Varieties: |
Algerite
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Synonyms: |
Marialite
(of von Roth), Marialith, Mizzonite
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Crystal
Data
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Crystallography:
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Tetragonal - Dipyramidal
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Crystal
Habit:
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TCrystals
prismatic, typically with flat pyramidal terminations,
striated || [001], to 1.5 m; granular, massive.
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Twinning:
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None
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Physical
Properties
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Cleavage: |
Distinct on
{100} and {110}
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Fracture: |
Irregular/uneven,
conchoidal
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Tenacity:
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Very
brittle
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Moh's
Hardness: |
5.5
- 6.0
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Density:
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2.50
- 2.62 (g/cm3)
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Luminescence:
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Commonly
fluoresces
orange to bright yellow or red under SW and/or LW
UV light. |
Radioactivity:
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Not
Radioactive
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Optical
Properties
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Color: |
Colorless,
white, grey; pink, violet, blue, yellow, brown, orange-brown;
colorless in thin section.
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Transparency: |
Transparent
to opaque |
Luster: |
Vitreous,
pearly, resinous |
Refractive
Index: |
1.532
- 1.550
Uniaxial ( - )
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Birefringence: |
0.007
- 0.009
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Dispersion: |
n/a |
Pleochroism: |
None
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Occurances
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Geological
Setting: |
Typically
in regionally metamorphosed rocks, especially marbles,
calcareous gneisses, granulites, and greenschists. Also
in skarns, some pegmatites, pneumatolytically or hydrothermally
altered mafic igneous rocks, and ejected volcanic blocks.
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Common
Associations: |
Plagioclase,
Garnet, Pyroxenes, Amphiboles, Atitanite, Zircon.
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Common
Impurities: |
Fe,
Ca, K, S
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Type
Locality: |
Pianura, Phlegrean Fields, Naples Province, Phlegrean Volcanic complex, Campania, Italy
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Year
Discovered: |
1866
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View
mineral photos: |
Marialite
Mineral Photos and Locations |
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More
Information
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Mindat.org
Webmineral.com
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Marialite was first described in 1866 for an occurrence in the Phlegrean Volcanic complex, Campania, Italy. Marialite was named in 1866 by German mineralogist Gerhard vom Rath (1830-1888) in honor of his wife, Maria Rosa vom Rath (1830-1888).
Marialite is a member of the Scapolite Group of minerals that includes Kembleite,
Marialite,
Meionite and Silvialie. Marialite
also belongs to the Marialite-Meionite series.
Marialite is the sodium chloride rich end member and
Meionite is the calcium carboniate rich end member with
Wernerite as a possible intermediate member of the series.
Although Wernerite is mostly an obsolete name now it
may be deserving of species status (see Dana, 8th Ed.).
Scapolite
is generally used as a mineral species name but actually
refers to the Marialite-Meionite series,
not an individual mineral name or the full Scapolite
Group, so excludes Kembleite and Silvialite. The name
Scapolite is now often used as a generic term when the
exact chemical composition of a specimen in the Marialite-Meionite solid
solution series has not been determined. Distinguishing the Scapolite minerals from each other is difficult as
they differ only slightly in density and index of refraction,
increasing in both with increasing calcium content.
It is because of this closeness in properties and yet seemingly
very different chemistries that Scapolite has had its share of
pseudonyms.
Wernerite was the most common alternate name for the Scapolite
series, but now it has mostly disappeared from use.
A few other names such as Mizzonite and Dipyre as well as Marialite and
Meionite have been used as names for the entire Scapolite series.
Marialite commonly fluoresces orange to bright yellow or red under SW and/or LW UV light.
Most
specimens are intermediate in the series; some localities
for highly sodic materials include: at Pianura, west
of Naples, Campania, Italy. From Russia, in the Slyudyanka
region, near Lake Baikal, Siberia. In the USA, at Hamburg
and Franklin, Sussex County, New Jersey; at Natural
Bridge, Je®erson County, Macomb, St. Lawrence County,
and Olmsteadville, Essex County, New York; from French
Creek, Chester County, Pennsylvania. In Canada, at Bear
Lake, Pontiac County, Quebec, and Bancroft, Ontario.
From the La Panchita mine, near Ayoquezco, Oaxaca, Mexico.
From Serra da Chibita, Rio Pardo, Minas Gerais, Brazil.
At Tsarasaotra and Betroka, Madagascar. From Mpwapwa,
Morogoro region, Dodoma, Tanzania. In the Mogok district,
Myanmar (Burma).
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